Product ID:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE, IEAT1784
MSDS Date:12/12/1997
FSC:6830
NIIN:00N089234
Status Code:A
MSDS Number: CHTTP

FISHER SCIENTIFIC

1 REAGENT LANE
FAIRLAWN, NJ 07410
US

Emergency Phone: 703-527-3887;800-424-9300(CHEMTREC)

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM/1250 STEL

IN HUMANS. ADRENOMIMETICS (E.G.,

RTECS: 9999999ZZ

USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CFC'S

RTECS: 9999999ZZ

REMOVE TO FRESH AIR IMMED. IF NOT

RTECS: 9999999ZZ

CAUSES CARD SENSIT TO

RTECS: 9999999ZZ

DO NOT USE ADRENERGIC AGENTS SUCH AS EPINEPHRINE OR

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50 (ORAL RAT): 43 GM/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: IRRIT, TEARING, & BURNING
PAIN. MAY CAUSE CONJ. SKIN: MAY CAUSE IRRIT. PRLNG &/OR RPTD CONT
MAY CAUSE DEFAT & DERM. INGEST: LGE AMTS MAY CAUSE GI IRRIT.
EXPECTED TO BE LOW INGEST HAZ. INH AL: HIGH CONCS MAY CAUSE CNS
EFTS INCL HDCH, DIZZ, UNCON & COMA. VAP REDUCES OXYGEN AVAIL FOR
BRTHG. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: MAY CAUSE RESP TRACT IRRIT. MAY CAUSE
HEART DISTURBS, POSS LEADING TO CARD ARREST & DEATH. MAY CAUSE
NARCOTIC EFTS. CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE DEFAT &
DERM. CHLOROFLUOROCARBON ( CFC) MATLS HAVE PRDCED SENSIT OF
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT
(ING 2)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS,
OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: FLUSH W/PLENTY
OF SOAP & WATER FOR AT LEAST 15 MINS WHILE REMOVING CONTAM CLTHG &
SHOES. GET MED AID IF IRRIT DEVELOPS/PERSISTS.WASH CLTHG BEFORE
REUSE. INGEST: IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF
MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERS. GET MED
AID. (ING 4)

Flash Point:NONE
Extinguishing Media:FOR SMALL FIRES, USE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE/CHEM FOAM. USE EXTING MEDIA APPROP FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA AND
FULL PROTECTIVE EQUIPMENT . COOL CONTAINERS WITH FLOODING
QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT.
Unusual Fire/Explosion Hazard:DURING FIRE, IRRITATING & HIGHLY TOX
GASES MAY BE GENERATED BY THERMAL DECOMP/COMBUST. VAPS MAY BE FLAM
IN VESSELS OF ADEQ SIZE. VAPS MAY BE HVR/AIR. (SUP DAT)

Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED. ABSORB SPILL WITH INERT MATERIAL (E.G., DRY SAND OR
EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. REMOVE ALL
SOURCES OF IGNITION. PROVIDE V ENTILATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONT W/SKIN & EYES. AVOID INGEST
& INHAL. KEEP FROM CONT W/OXIDIZING MATLS. STORE IN COOL, DRY,
WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLES.
Other Precautions:USE W/ADEQ VENT. KEEP AWAY FROM METALS. KEEP CONTRS
TIGHTLY CLSD. DO NOT STORE IN ALUMINUM CONTRS. NO SMKNG IN AREA OF
USE. DO NOT USE IN GEN VICIN OF ARC WELDING, OPEN FLAMES/HOT SURFS.
HEAT &/OR UV RADIATION MAY CAUSE FORM OF (SUP DAT)

Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN
NECESSARY.
Ventilation:GOOD GEN VENT SUFFICIENT TO CTL AIRBORNE LEVELS. USE
PROCESS ENCLOSURE, LOC EXHST VENT/OTHER ENGINEERING CTLS (SUP DAT)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
EXPLO HAZ: THEY CAN SPREAD ALONG GROUND & COLLECT IN LOW/CONFINED
AREAS. THERMAL DECOMP PRODS MAY INCL CHLORIDES, FLUORIDES, &
PHOSGENE . MATLS TO AVOID: ALLOY, TITANIUM, ZINC, MAGNESIUM, & BERY
LLIUM. OTHER PREC: CHLORIDES, FLUORIDES, &/OR PHOSGENE . VENT: TO
CTL AIRBORNE LEVELS BELOW REC EXPOS LIMITS.

Boiling Pt:B.P. Text:114F,46C
Melt/Freeze Pt:M.P/F.P Text:-34F,-36C
Vapor Pres:273 @ 20C
Vapor Density:6
Spec Gravity:1.6
Evaporation Rate & Reference:0.45 (ACETONE=1)
Solubility in Water:0.028%
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH WEAK ETHEREAL ODOR.

Stability Indicator/Materials to Avoid:YES
ALKALI/ALKALINE EARTH METALS SUCH AS SODIUM, POTASSIUM, ALUMINUM,
BARIUM, LITHIUM, SAMARIUM, SODIUM-POTASSIUM (SUP DAT)
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES,
METALS, STRONG OXIDANTS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CARBON
MONOXIDE, IRRITATING & TOX FUMES & GASES, CARBON DIOXIDE, HYDROGEN
FLUORIDE.

Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. NOT LISTED AS A MATERIAL BANNED FROM
LAND DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.